利用显微拉曼光谱技术鉴别印文形成时间的应用研究

韩伟 1, 2*,黄建同1,陈维娜1,王皓1

光散射学报 ›› 2017, Vol. 29 ›› Issue (1) : 44-49. DOI: 10.13883/j.issn1004-5929.201701002
化学和生物研究中的应用

利用显微拉曼光谱技术鉴别印文形成时间的应用研究

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Research on Dating of Inkpad Seals by Micro-Raman Spectroscopy

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摘要

采用激光显微拉曼光谱技术,选择10种不同品牌和型号的印泥(油)盖印印文的历时性样本,利用印文拉曼光谱中的1089 cm-1和1235 cm-1处特征峰的相对面积值(I)分析纸张、温度、热老化因素对印文形成时间的影响,探讨盖印时间与峰面积相对值(I)的关系。结果表明,I值随时间呈现规律性变化,尤其在近期内盖印印文的变化规律明显,适用于印文形成时间的鉴别,是一种准确、无损的检验方法。

Abstract

Objective taking advantage of Micro-Raman spectroscopy technology , samples of inkpad seals were impressed with 10 different brands of inks. To analysis the factors of paper,temperature and heat condition by relative area value(I)of characteristic peaks with 1089 cm-1 and 1235 cm-1 in Raman spectrum, in order to discuss the relation between relative area value (I) and dating of inkpad seals. The relative area value (I) showed a regular change with time, especially the stamp of impression in the near time . Micro-Raman spectroscop is a useful method  with accurate, non-destructive properties to determine the formation time of inkpad seals.

关键词

拉曼光谱 / 盖印时间 / 无损检验 / 司法鉴定

Key words

Raman spectroscopy / Dating of Stamp Impressions / Non-destructive detection / Forensic science

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韩伟 1, 2*,黄建同1,陈维娜1,王皓1. 利用显微拉曼光谱技术鉴别印文形成时间的应用研究. 光散射学报. 2017, 29(1): 44-49 https://doi.org/10.13883/j.issn1004-5929.201701002
. Research on Dating of Inkpad Seals by Micro-Raman Spectroscopy. Chinese Journal of Light Scattering. 2017, 29(1): 44-49 https://doi.org/10.13883/j.issn1004-5929.201701002

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