纳米银沉积在不同基底上的表面增强拉曼效果

赵淑慧,李莎莎,戚海艳,陈华才

光散射学报 ›› 2017, Vol. 29 ›› Issue (3) : 216-221. DOI: 10.13883/j.issn1004-5929.201703006
表面增强拉曼散射技术

纳米银沉积在不同基底上的表面增强拉曼效果

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Substrates of Silver Nanoparticles on Different Plates for Surface Enhanced Raman Spectroscopy

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摘要

采用化学还原法制备了花状纳米银凝胶溶胶,沉积在硅片、二氧化钛薄膜、玻璃上,制备得到了AgNP@Si,AgNP@TiO2,AgNP@G 3种表面增强拉曼基底。以罗丹明6G(R6G)为探针分子,考察了3种基底的表面增强拉曼效果,重复性及均匀性。AgNP@TiO2和AgNP@Si的检出限为10-8mol·L-1,而AgNP@G的检出限为10-7 mol·L-1,AgNP@Si的重复性和均匀性最优。结果表明,AgNP@Si的SERS增强效果最佳,并具有制备简单,重复性和均匀性好等优点。

Abstract

We prepared the flower-like silver nanoparticles by using chemical reduction method and deposited it on silicon wafer, TiO2 film and glass plate (AgNP@Si, AgNP@TiO2, AgNP@G) separately in order to get substrates for surface enhanced Raman spectroscopy. The repeatability, sensitivity and uniformity of these substrates were studied by using R6G solution. The detection limit of AgNP@TiO2 and AgNP@Si was 10-8 mol·L-1, while the AgNP@G was 10-7 mol·L-1. Meanwhile, Repeatability and uniformity of AgNP@Si are better than others. The results show that the AgNP@Si has the best Raman enhancement effect, the simple preparation, good repeatability and uniformity.

关键词

SERS / 基底 / 纳米银 / 纳米二氧化钛膜 / 硅片

Key words

SERS / substrates / silver nanoparticle / TiO2 film / Si wafer

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赵淑慧,李莎莎,戚海艳,陈华才. 纳米银沉积在不同基底上的表面增强拉曼效果. 光散射学报. 2017, 29(3): 216-221 https://doi.org/10.13883/j.issn1004-5929.201703006
. Substrates of Silver Nanoparticles on Different Plates for Surface Enhanced Raman Spectroscopy. Chinese Journal of Light Scattering. 2017, 29(3): 216-221 https://doi.org/10.13883/j.issn1004-5929.201703006

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