上川岛青花彩瓷的光谱分析

doi:10.13883/j.issn1004-5929.202001009

光散射学报 ›› 2020, Vol. 32 ›› Issue (1) : 72-77. DOI: 10.13883/j.issn1004-5929.202001009

化学和生物研究中的应用

上川岛青花彩瓷的光谱分析

胡林顺¹, 曾庆光^1,2*, 温锦秀¹, 陈子坤¹, 张国雄²

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Spectral Analysis of Blue-and-White porcelain on Shangchuan Island

HU Linshun¹, ZENG Qingguang^1,2*, WEN Jinxiu¹, CHEN Zikun¹, ZHANG Guoxiong²

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摘要

本文采用X射线荧光光谱和显微拉曼光谱对广东省江门市上川岛“花碗坪”遗址发掘的青花彩绘瓷片进行成分的元素和结构分析。结果表明瓷片的瓷胎具有低铝、高硅、高钾的特点。红褐色颜料采用的是釉上彩工艺,显色为赤铁矿,主要的助溶剂为氧化钾;蓝色颜料采用的是釉下彩,显色为国产的钴土和进口钴土矿混合,助溶剂主要为氧化钙。通过结合遗址当时历史背景和计算F函数可以推断出瓷片来源于明末清初福建省的漳州漳窑。

Abstract

In this work, X-ray fluorescence spectroscopy and micro-Raman spectroscopy were used to analyze the components and molecular structures of blue-and-white porcelain excavated from Huawanping site in Shangchuan Island, Jiangmen City, Guangdong Province. It shows that the characteristics of the porcelain body are low aluminum, high silicon and high potassium. The main component of reddish-brown pigment is hematite employed with the glaze-on-color technology. The main component of blue pigment was the mixed with domestic cobalt soil and imported cobalt ore by the under-glaze color technology. It can be deduced that the porcelain originated from Zhangzhou kiln in Fujian Province at the late Ming or early Qing dynasties by combination historical background of the site at that time with the calculation of F function.

Key words

blue-and-white porcelain / reddish-brown pigment / glaze-on-color / blue pigment / under-glaze color

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胡林顺, 曾庆光, 温锦秀, 陈子坤, 张国雄. 上川岛青花彩瓷的光谱分析. 光散射学报. 2020, 32(1): 72-77 https://doi.org/10.13883/j.issn1004-5929.202001009

HU Linshun, ZENG Qingguang, WEN Jinxiu, CHEN Zikun, ZHANG Guoxiong. Spectral Analysis of Blue-and-White porcelain on Shangchuan Island. Chinese Journal of Light Scattering. 2020, 32(1): 72-77 https://doi.org/10.13883/j.issn1004-5929.202001009

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基金

江门市科技计划项目(No.(2017) 307, (2017) 149, (2018) 352), 广东省科技项目(No. 2016A020225009), 广东省协同育人平台(No. (2016)31),广东省高校光电子材料及应用重点实验室 (No:2017KSYS011) 和江门市创新领军人才项目(江人才通[2019]7号)。

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Received	Revised	Published
2019-08-12	2019-09-07	2020-03-10
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2022-08-19

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