基于双硫腙修饰银纳米材料的铅离子循环表面增强拉曼检测

doi:10.13883/j.issn1004-5929.202101002

光散射学报 ›› 2021, Vol. 33 ›› Issue (1) : 16-23. DOI: 10.13883/j.issn1004-5929.202101002

表面增强拉曼散射技术

基于双硫腙修饰银纳米材料的铅离子循环表面增强拉曼检测

郭艳艳¹, 田怀香², 李原婷¹, 李丹^1*

作者信息 +

Dithizone Modified Silver Nanomaterials for Recyclable Surface-enhanced Raman Spectroscopy Detection of Lead Ions

GUO Yanyan¹, TIAN Huaixiang², LI Yuanting¹, LI Dan^1*

Author information +

History +

摘要

该研究以重金属铅离子(Pb²⁺)为研究对象,构建双硫腙修饰的银纳米颗粒,利用氧化-还原法和表面增强拉曼技术,成功实现了对铅离子的循环表面增强拉曼检测。该功能材料对铅离子的检测响应范围为1 nM~10 μM,检出限可达0.35 nM,将该方法用于实际环境水样中铅离子的检测,回收率为91.6%~106.8%,相对标准偏差在4.1%~7.9%之间。该方法具有操作简单、测定快速和可重复使用等特点,因而在环境样品中重金属离子快速检测方面具有巨大的应用前景。且该研究对环境中其他污染物的研究提供了重要的参考信息。

Abstract

The study took heavy metal lead ions (Pb²⁺) as the research object, constructed dithizone-modified silver nanoparticles, and successfully realized the cyclic surface-enhanced Raman detection of lead ions by using redox method and surface enhanced Raman technology. The detection response range of functional materials to lead ions is 1nM~10μM, and the detection limit can reach 0.35nM. Using the method to detect lead ions in actual environmental water samples, the recovery rate is 91.6%~106.8%, and the relative standard deviation is between 4.1% and 7.9%. The method has the characteristics of convenience, rapidity and reusability, and has a huge application prospect in the rapid detection of heavy metal ions in environmental samples.

导出引用

郭艳艳, 田怀香, 李原婷, 李丹. 基于双硫腙修饰银纳米材料的铅离子循环表面增强拉曼检测. 光散射学报. 2021, 33(1): 16-23 https://doi.org/10.13883/j.issn1004-5929.202101002

GUO Yanyan, TIAN Huaixiang, LI Yuanting, LI Dan. Dithizone Modified Silver Nanomaterials for Recyclable Surface-enhanced Raman Spectroscopy Detection of Lead Ions. Chinese Journal of Light Scattering. 2021, 33(1): 16-23 https://doi.org/10.13883/j.issn1004-5929.202101002

参考文献

[1]Taghdisi S M, Danesh N M, Lavaee P, et al. A novel colorimetric triple-helix molecular switch aptasensor based on peroxidase-like activity of gold nanoparticles for ultrasensitive detection of lead (II)[J]. RSC Advances, 2015, 5(54):43508-43514.
[2]Pattanayak S, Swarnkar A, Paik, P, et al. Seed Geometry and Hydrogen Bonding Dependent Plasmonic Tuning of Silver Nanocrystals in Citrate-hydrazine Matrix and SERS Spectroscopy Detection of Chromium. RSC Advances, 2017, 7(73): 45911-45919.
[3]孙冲, 王瑞, 郭亚. 环境中重金属离子检测方法研究综述[J]. 上海环境科学集, 2020, 000(001):18-20. (Sun Chong, Wang Rui, Guo Ya. Review of research on detection methods of heavy metal ions in the environment[J]. Shanghai Environmental Science Collection, 2020, 000(001):18-20.)
[4]Zhong G W, Liu J X, Liu X Y, A Fast Colourimetric Assay for Lead Detection Using Label-Free Gold Nanoparticles (AuNPs)[J]. Micromachines, 2015, 6(4):462-472.
[5]钱志娟, 施美荣, 郑蓉, 等. 基于金核铂壳纳米粒子的铅离子比色检测方法[J]. 分析试验室, 2019, 38(4):399-404. (Qian Zhijuan, Shi Meirong, Zheng Rong, etc. The colorimetric detection method of lead ion based on gold core platinum shell nanoparticles[J]. Chinese Journal of Analysis Laboratory, 2019, 38(4): 399-404.)
[6]Shi Y, Chen N, Su Y Y, et al. Silicon Nanohybrid-Based SERS Chips Armed with an Internal Standard for Broad-Range, Sensitive and Reproducible Simultaneous Quantification of Lead (II) and Mercury (II) in Real Systems. Nanoscale 2018, 10(8): 4010-4018.
[7]Frost M S, Dempsey M J, Whitehead D E, Highly sensitive SERS detection of Pb2+ ions in aqueous media using citrate functionalised gold nanoparticles[J]. Sensors and Actuators B-Chemical, 2015, 221, 1003-1008.
[8]庞永丰, 罗杨合, 吴凤莲, 等. 基于DNA酶表面增强拉曼的皮蛋中痕量Pb²⁺检测方法[J]. 食品研究与开发, 2019, 40(24):159-166 (Pang Yongfeng, Luo Yanghe, Wu Fenglian, et al. A DNA Enzyme SERS Method for Determination of Trace Pb²⁺ in Pre-served Eggs [J]. Food Research and Development, 2019, 40(24): 159-166.)
[9]Zhang W, Xiong B, Chen L, et al. Toxicity Assessment of Chlorella Vulgaris and Chlorella Protothecoides Following Exposure to Pb (II)[J]. Environmental Toxicology and Pharmacology,2013, 36(1): 51-57.
[10]李瑞琴, 于安芬, 胡梅. 芽菜中铅残留及食用安全性分析[J].北方园艺, 2009(2) :75-76. (Li Ruiqin, Yu Anfen, Hu Mei. Analysis of Lead Residue in Sprouts and Edible Safety[J]. Northern Horticulture, 2009(2): 75-76.)
[11]徐守霞, 王斌. 双硫腙法测定蔬菜中铅残留的研究[J]. 安徽农业科学, 2016, 44(14):109-110. (Mahaya Aisijiang, Bahar Guli Biektulxun. Determination of HeavyMetal Lead in Mineral Samples by Dithizone Color Spectrophotometry[J]. Anhui Agricultural Sciences, 2016, 44(14):109-110.)
[12]蔡艳荣, 孙全敏. 大孔树脂富集-火焰原子吸收法测定蔬菜中的铅和镉[J]. 科学技术与工程, 2014, 14(4): 265-268. (Cai Yanrong, Sun Quanmin. Macroporous Resin Enrichment-flame Atomic Absorption Method for Determination of Lead and Cadmium in Vegetables[J]. Science Technology and Engineering, 2014, 14(4): 265-268.)
[13]马智玲, 赵文, 李凌云, 等. 气相色谱-三重四极杆串联质谱法快速测定蔬菜水果129 种农药的残留量[J]. 色谱, 2013, 31(3): 228-239. (Ma Zhiling, Zhao Wen, Li Lingyun, et al. Gas Chromatography-triple Quadrupole Tandem Mass Spectrometry for Rapid Determination of 129 Pesticide Residues in Fruits and Vegetables[J]. Chromatography, 2011, 31(3): 228-239.)
[14]陈江, 费勇, 吴锦芳, 等. 氯化锂增敏-电感耦合等离子体原子发射光谱法测定地表水中铅锰[J]. 冶金分析, 2010, 30(4):41-44. (Chen Jiang, Fei Yong, Wu Jinfang, et al. Determination of Lead and Manganese in Surface Water by Lithium Chloride Sensitization-inductively Coupled Plasma Atomic Emission Spectrometry[J]. Metallurgical Analysis, 2010, 30(4):41-44.)
[15]Benjaber S, Peveler W J, Quesadacabrera R, et al. Photo-induced enhanced Raman spectroscopy for universal ultra-trace detection of explosives, pollutants and biomolecules [J]. Nature Communications, 2016, 7:12189.
[16]陶晨阳, 宁欢, 陈海艺,等. 基于单个花状银纳米颗粒的表面增强拉曼散射效应研究[J]. 光散射学报, 2020, 032(001):46-51. (Tao Chenyang, Ning Huan, Chen Haiyi, et al. Surface-enhanced Raman Scattering Study of Individual Flower-like Silver Nanoparticles[J]. The Journal of Light Scatterin, 2020, 032(001):46-51.)
[17]陈宇宇, 彭俊瑛, 李光照, 等. 表面增强拉曼光谱法检测儿童化妆品中二噁烷含量的研究[J]. 光散射学报,2015, 27(4): 316-319. (Chen Yuyu, Peng Junying, Li Guangzhao, et al. Dioxane Detection of Children Cosmetics Using surface-enhanced Raman Spectroscopy[J]. The Journal of Light Scatterin, 2015, 27(4): 316-319.)
[18]Mudasir M, Baskara R A, Suratman A, et al. Simultaneous Adsorption of Zn(II) and Hg(II) Ions on Selective Adsorbent of Dithizone-Immobilized Bentonite in the Presence of Mg(II) Ion[J]. Journal of Environmental Chemical Engineering, 2020, 8(4):104002.
[19]Agnihotri S, Mukherji S, Mukherji S. Immobilized silver nanoparticles enhance contact killing and show highest efficacy: elucidation of the mechanism of bactericidal action of silver, Nanoscale, 2013, 5:7328-7340.
[20]刘小龙, 王旭, 徐蔚青, 等. 双硫腙在银溶胶中的表面增强拉曼光谱(SERS)研究[J]. 光散射学报, 2004, 16(002):122-126. (Liu Xiaolong, Wang Xu, Xu Weiqing, et al. Surface-enhanced Raman Spectroscopy (SERS) of Dithizone in Silver Sol[J]. The Journal of Light Scatterin, 2004, 16(002):122-126.)

基金

国家自然科学基金项目(No. 21507089, 21976123);上海市科技委员会农业领域重点项目(No. 19391901800); 海南省热带药用植物研究开发重点实验室开放课题(KF202001)

PDF(1516 KB)

364

Accesses

Citation

Detail

段落导航

摘要
Abstract
关键词
Key words
引用本文
参考文献
基金

Received	Revised	Published
2020-08-05	2020-09-25	2021-03-10
Issue Date
2021-10-12

选择文件类型/文献管理软件名称

选择包含的内容

摘要

Abstract

关键词

Key words

引用本文

{{custom_sec.title}}

{{custom_sec.title}}

参考文献

{{custom_fnGroup.title_cn}}

脚注

基金