氨基磺酸型两性离子化合物热力学性质研究

青卿, 刘世杰, 汪词明, 何玉韩, 罗江水

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光散射学报 ›› 2024, Vol. 36 ›› Issue (2) : 134-141. DOI: 10.13883/j.issn1004-5929.202402005

氨基磺酸型两性离子化合物热力学性质研究

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Study on the Thermodynamic Properties of Sulfamic acid-Based Zwitterionic Compounds

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摘要

选取了四种氨基磺酸型两性离子化合物:氨基磺酸(SA)、氨基甲磺酸(AMA)、牛磺酸(TAU)和3-氨基-1-丙磺酸(APA),利用傅里叶变换红外光谱(FT-IR)研究了四种物质的两性离子结构。红外光谱中NH3+伸缩振动峰和SO3−的伸缩振动峰表明四种物质以两性离子化合物的形式存在。通过差示扫描量热法(DSC)和热重分析(TGA)研究了相变温度和热稳定性。结果表明四种两性离子化合物都是熔融的同时伴随着分解,并且TAU的热稳定性最好。

Abstract

Four zwitterionic compounds of sulfamic acid type: sulfamic acid (SA), aminomethanesulfonic acid (AMA), taurine (TAU), and 3-amino-1-propanesulfonic acid (APA) were selected. Fourier-transform infrared spectroscopy (FT-IR) was employed to investigate the zwitterionic structures of these compounds. The results demonstrate the presence of zwitterionic forms for all four substances, as evidenced by the presence of stretching vibrational peaks for NH3+ and SO3− in the infrared spectra. Phase transition temperatures and thermal stability were analyzed using differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The results indicate that all four zwitterionic compounds undergo melting accompanied by decomposition, with taurine exhibiting the highest thermal stability.

关键词

两性离子化合物 / 傅里叶变换红外光谱 / 热力学 / 差示扫描量热法 / 恒温热重法

Key words

zwitterionic compounds / Fourier transform infrared spectroscopy / thermodynamics / differential scanning calorimetry / isothermogravimetric approach

引用本文

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青卿, 刘世杰, 汪词明, 何玉韩, 罗江水. 氨基磺酸型两性离子化合物热力学性质研究. 光散射学报. 2024, 36(2): 134-141 https://doi.org/10.13883/j.issn1004-5929.202402005
Qing Qing, Shijie Liu, Ciming Wang, Yuhan He, Jiangshui Luo. Study on the Thermodynamic Properties of Sulfamic acid-Based Zwitterionic Compounds. Chinese Journal of Light Scattering. 2024, 36(2): 134-141 https://doi.org/10.13883/j.issn1004-5929.202402005

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基金

本文获国家自然科学基金(22378270、21776120)、四川省科技计划(2022ZYD0016、2023JDRC0013)、福建省自然科学基金(2023J01254)、呼和浩特市科技计划项目(2023-揭榜挂帅-高-3)、广东省燃料电池技术重点实验室2022年开放基金(基金号:FC202218、FC202206)和2023年四川大学研究生培养教育创新改革项目(2023JXAL008)资助。
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