Well-crystallized bulk of Re₃N was synthesized through a High-Pressure Solid-State Metathesis (HPSSM) reaction. The structural characterizations and compositions of as-prepared samples were determined by X-ray powder diffraction (XRD), scanning electron microscope (SEM) and energy dispersive X-ray analysis (EDS), which indicated high crystalline quality of Re₃N. The vibrational properties of Re₃N lattices were studied by the temperature dependence on Raman spectroscopy between 77 K and 873 K. With the temperature increasing, the red-shift and broadening of Raman bands of Re₃N could be well fitted using a model involving three- and four-phonon decay processes. Our fitting results indicated that the three-phonon decay processes were dominant over the four-phonon ones at high temperatures. The bulk modulus B0=417 GPa for Re₃N was determined by high-pressure synchrotron radiation research indicating that Re₃N synthesized through HPSSM reaction may be a potential superhard materials.