Based on Ultraviolet Non-line-of-sight Single Scattering Link in coplanar Model, this paper analyzed non-coplanar mode when transmitter and receiver do not face each other. Three non-coplanar cases are analyzed in this paper, one is either of transceiver does not face the other part, one is both of transceiver do not face each other. This paper mainly analyzes three non coplanar cases, the first kind is either part faces to the other part; The other two kinds are both parts do not face to each other on the same side and different sides. The simulation show that the former two kinds can communicate, but receiving power is not very high. The third kind can not communicate, because it is difficult to form a common scattering volume in the air.